Chiral Reagents for Asymmetric SynthesisLeo A. Paquette Derived from the renowned, Encyclopedia of Reagents for Organic Synthesis (EROS), the related editors have created a new handbook which focuses on chiral reagents used in asymmetric synthesis and is designed for the chemist at the bench. This new handbook follows the same format as the Encyclopedia, including an introduction and an alphabetical arrangement of the reagents. As chiral reagents are the key for the successful asymmetric synthesis, choosing the right reagents is essential, in this handy reference the editors give details on how to prepare, store and use the reagents as well as providing key reactions to demonstrate where reagents have been successfully used.
All reagents included will be added to e-EROS – please visit the site where you can gain access to over 50,000 reactions and 3,800 of the most frequently consulted reagents. Visit: www.interscience.wiley.com/eros |
Contents
Ethylene12bisη³4567tetrahydro1 | 1 |
Organic Synthesis Procedures Featuring Chiral | 7 |
carboxylate | 9 |
SAcetocarbonylcyclopentadienyltriphenyl | 21 |
21 | 100 |
105 | 157 |
R2tButyl6methyl4H13dioxin4one | 163 |
107 | 165 |
356 | 443 |
361 | 452 |
365 | 462 |
tLeucine tButyl Ester | 468 |
2Amino3methyl11diphenyl1butanol | 509 |
Cyclopentadienyl35dimethoxybenzyl | 535 |
1heptan2ol | 539 |
289 | 542 |
1S12bisdiphenylphosphinoferrocenylethylamine 115 | 241 |
R+tButyl 2pTolylsulfinylacetate | 249 |
10Camphorsulfonyl Chloride | 255 |
Camphorylsulfonyloxaziridine | 264 |
Tetrafluoroborate | 293 |
Glycidol | 329 |
+NFluoro21033dichlorocamphorsultam | 343 |
NGlyoxyloyl2Rbornane102sultam | 352 |
S3Hydroxy5methyl24imidazolidinedione | 360 |
353 | 428 |
354 | 437 |
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Common terms and phrases
a-amino acetate Acta acyl addition adducts affords alcohols aldehydes aldol reaction alkenes alkyl allylic amines amino acids Analysis of Reagent Angew Asymmetric Synthesis Asymmetry 1991 BuLi carbonyl catalyst CHCl3 Chem Chim chiral auxiliary chiral ligand chloride CO2Et CO2H CO2Me Commun./J complex compounds Corey corresponding cyclic cycloaddition derivatives diastereomeric diastereoselectivity Diels-Alder reaction ee eq enantiomer enantiomeric excess enantiomerically pure enantioselective Enders Engl enolate epoxidation equiv esters Et2O Et3N ether EtOH Evans Form Supplied Helv hydrogenation hydrolysis i-Pr isomer ketones Lewis acid LiAlH4 lithium MeO2C MeOH methyl Mukaiyama Noyori nucleophiles obtained OH OH optically active Organomet oxidation p-Tol Perkin Trans Physical Data PPh2 Precautions Preparative Methods prochiral pseudoephedrine racemic reduction Related Reagents Seebach Solubility solvents stereoselective Storage substituents substrates Synlett Synth t-Bu Tetrahedron Lett tion toluene Trost Yamamoto yield